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trans-Chloridobis[(Z)-1-imino-1-methoxyethane-κN](triphenylphosphane-κP)platinum(II) chloride monohydrate
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Titel: |
trans-Chloridobis[(Z)-1-imino-1-methoxyethane-κN](triphenylphosphane-κP)platinum(II) chloride monohydrate |
In: | Acta Crystallographica Section C Crystal Structure Communications, 68, 2012, 11, S. m300-m302 |
veröffentlicht: |
International Union of Crystallography (IUCr)
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Umfang: | m300-m302 |
ISSN: |
0108-2701 |
DOI: | 10.1107/s0108270112040826 |
Zusammenfassung: | <jats:p>The title compound, [PtCl(C<jats:sub>3</jats:sub>H<jats:sub>7</jats:sub>NO)<jats:sub>2</jats:sub>(C<jats:sub>18</jats:sub>H<jats:sub>15</jats:sub>P)]Cl·H<jats:sub>2</jats:sub>O or<jats:italic>trans</jats:italic>-[PtCl{<jats:italic>Z</jats:italic>-HN=C(Me)OMe}<jats:sub>2</jats:sub>(PPh<jats:sub>3</jats:sub>)]Cl·H<jats:sub>2</jats:sub>O, crystallizes from an acetone solution of isomeric<jats:italic>trans</jats:italic>-[PtCl{<jats:italic>E-</jats:italic>HN=C(Me)OMe}<jats:sub>2</jats:sub>(PPh<jats:sub>3</jats:sub>)]Cl. The two HN=C(Me)OMe ligands show typical π-bond delocalization over the N—C—O group [Cini, Caputo, Intini & Natile (1995).<jats:italic>Inorg. Chem.</jats:italic><jats:bold>34</jats:bold>, 1130–1137] and have the unprecedented<jats:italic>Z–anti</jats:italic>configuration. The relative orientation of the imino ether ligands is head-to-tail.</jats:p> |
Format: | E-Article |
Quelle: | International Union of Crystallography (IUCr) (CrossRef) |
Sprache: | Unbestimmt |